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I never knew this!!
so I looked it up for Photoshop CS this is how you do it - probably similar for PSE?
Choose Edit > Purge, and choose the item type or buffer you want to clear. If already empty, the item type or buffer is dimmed.
Important: The Purge command permanently clears from memory the operation stored by the command or buffer; it cannot be undone. For example, choosing Edit > Purge > Histories deletes all history states from the History palette. Use the Purge command when the amount of information held in memory is so large that Photoshop's performance is noticeably diminished.
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